(R)-(-)-1-[(S)-2-(DI(3,5-BIS-TRIFLUOROMETHYLPHENYL)PHOSPHINO)FERROCENYL]ETHYLDI(3,5-DIMETHYLPHENYL)PHOSPHINE - Names and Identifiers
Name | (R)-(-)-1-[(S)-2-(DI(3,5-BIS-TRIFLUOROMETHYLPHENYL)PHOSPHINO)FERROCENYL]ETHYLDI(3,5-DIMETHYLPHENYL)PHOSPHINE
|
Synonyms | (R)-(-)-1-((S)-2-(Di(3,5-Bis-Trifluoromethylphenyl)Phosphino)Ferr (R)-1-{(S)-2-[Bis[3,5-bis(trifluoromethyl)phenyl]phosphino]-ferrocenyl}ethyldi(3 (R)-(-)-1-{(S)-2-[Bis(3,5-di-trifluoromethylphenyl)phosphino]ferrocenyl}ethyldi-3,5-xylylphosphine, min (R)-(-)-1-[(S)-2-(DI(3,5-BIS-TRIFLUOROMETHYLPHENYL)PHOSPHINO)FERROCENYL]ETHYLDI(3,5-DIMETHYLPHENYL)PHOSPHINE (R)-(-)-1-((S)-2-(Di(3,5-bis-trifluoromethylphenyl)phosphino)ferrocenyl)ethyl-di-(3,5-dimethylphenyl)phosphine
|
CAS | 166172-63-0
|
InChI | InChI=1/C39H31F12P2.C5H5.Fe/c1-21-9-22(2)12-30(11-21)52(31-13-23(3)10-24(4)14-31)25(5)34-7-6-8-35(34)53(32-17-26(36(40,41)42)15-27(18-32)37(43,44)45)33-19-28(38(46,47)48)16-29(20-33)39(49,50)51;1-2-4-5-3-1;/h6-20,25H,1-5H3;1-5H;/t25-;;/m0../s1 |
(R)-(-)-1-[(S)-2-(DI(3,5-BIS-TRIFLUOROMETHYLPHENYL)PHOSPHINO)FERROCENYL]ETHYLDI(3,5-DIMETHYLPHENYL)PHOSPHINE - Physico-chemical Properties
Molecular Formula | C44H36F12FeP210*
|
Molar Mass | 910.53 |
Specific Rotation(α) | -280° ±10° (c 0.5, CHCl3) |
Appearance | Powder |
Color | orange |
Storage Condition | under inert gas (nitrogen or Argon) at 2-8°C |
MDL | MFCD08561153 |
Physical and Chemical Properties | WGK Germany:3 |
(R)-(-)-1-[(S)-2-(DI(3,5-BIS-TRIFLUOROMETHYLPHENYL)PHOSPHINO)FERROCENYL]ETHYLDI(3,5-DIMETHYLPHENYL)PHOSPHINE - Risk and Safety
Risk Codes | 36/37/38 - Irritating to eyes, respiratory system and skin.
|
Safety Description | S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection.
|
WGK Germany | 3 |
HS Code | 29319090 |
(R)-(-)-1-[(S)-2-(DI(3,5-BIS-TRIFLUOROMETHYLPHENYL)PHOSPHINO)FERROCENYL]ETHYLDI(3,5-DIMETHYLPHENYL)PHOSPHINE - Introduction
(R)-(-)-1-[(S)-2-(DI(3,) PHOSPHINO)FERROCENYL]ETHYLDI (3,5-dimethylphenyl) PHOSPHINE is an organic compound with the following properties:
Nature:
-Appearance: a solid
-Molecular formula: C38H31F6FeP3
-Molecular weight: 748.45g/mol
-Melting point: About 160 ° C
-Solubility: Soluble in non-polar organic solvents, such as benzene, toluene, etc.
Use:
- (R)-(-)-1-[(S)-(DI(3, 2) PHOSPHINO)FERROCENYL]ETHYLDI (3,5-dimetylphenyl) PHOSPHINE is a kind of chiral catalyst, which is widely used in asymmetric synthesis.
-It can be used for asymmetric catalytic reactions, such as asymmetric hydrogenation, asymmetric reduction, etc.
-can also be used for asymmetric olefin addition reaction, asymmetric phase transfer catalytic reaction.
Method:
(R)-(-)-1-[(S)-2-(DI(3,) PHOSPHINO)FERROCENYL]ETHYLDI (3,5-dimethylphenyl) the preparation of phosphines is relatively complex and is usually carried out by methods of organic synthesis. The specific preparation scheme can be selected according to the experimental needs.
Safety Information:
The safety of this compound has not been fully evaluated. Please pay attention to personal protective measures during use. Before use, the Safety Data Sheet (MSDS) and technical instructions provided with the chemical should be carefully read, and the relevant experimental operation safety specifications should be followed. It must be done in well-ventilated laboratory conditions, avoiding contact with skin and eyes. In the case of accidental contact, immediately flush the affected area with water and seek medical help.
Last Update:2024-04-10 22:29:15